Fluid Rheology
Dimensionless viscoelastic ratios govern the time-dependent stress response of molten polymers and liquid coatings during high-speed fluid processing. Extrusion coating operations evaluate Deborah number relaxation by comparing internal polymer relaxation time against the mechanical residence time spent inside application nips. Values above unity signify elastic fluid behavior, whereas small values denote viscous flow.
Polymer Dynamics
Polymer melt streams experience severe extensional shear forces when passing through narrow extrusion dies onto moving paperboard substrates. High Deborah numbers indicate that polymer chains lack sufficient time to disentangle before entering cooling roll nips. Unrelaxed stresses cause internal tension within solidified barrier layers, leading to film neck-in and edge instability.
Adjusting resin temperature alters molecular relaxation rates, enabling processing lines to reach equilibrium during coating.
Coating Application
Liquid barrier formulations applied via curtain coaters rely on rapid stress dissipation to prevent film tearing and surface patterning. When Deborah number relaxation occurs too slowly, elastic stresses accumulate in the liquid curtain, generating ribbing defects across paper web surfaces. Converter lines modify line speed or coating viscosity to reduce the effective Deborah number during high-speed web runs.
Polyethylene extrusion onto porous board requires sufficient viscous flow to promote mechanical keying into surface fibres. Balancing relaxation dynamics ensures optimal heat seal performance, uniform barrier thickness and defect-free adhesion on liquid packaging board.