Effluent Testing
Standardized sealed-tube photometric analysis quantifies chemical oxygen demand in water streams by measuring dichromate oxidation under thermal digestion. Paper mills and packaging converting plants apply iso 15705 to monitor organic loading in process wastewater before discharge into public sewer networks or receiving rivers. Sealed glass cuvettes containing potassium dichromate and sulfuric acid consume oxidizable organic compounds during two hours of heating at one hundred fifty degrees Celsius.
Photometric measurement of chromium ion concentration changes yields chemical oxygen demand values without open reagent handling.
Digestion Chemistry
Chromium reduction inside sealed reaction vessels correlates linearly with organic carbon oxidation. Test procedures under iso 15705 measure remaining hexavalent chromium or generated trivalent chromium at specific optical wavelengths. Sealed cuvettes minimize hazardous chemical vapor exposure during digestion.
Interference Threshold
Chloride ions present in process white water react with silver catalysts, precipitating silver chloride and causing false positive oxygen demand readings. Testing protocols in iso 15705 mandate mercury sulfate additions to complex chloride ions up to specified concentration thresholds. High concentration starch additives or wet-strength resins in mill effluent elevate total organic load, requiring sample dilution to maintain optical transmission within calibration curves.
The standard applies strictly to clear or diluted aqueous samples and excludes solid pulper waste or dry paper samples.