Temporal Decay
Rate at which internal stress diminishes within a material held at a constant strain defines the stability of the mechanical bonds in a paper sheet. For cellulose networks, stress relaxation kinetics describe how the fibers and the hydrogen bonds between them rearrange over time to relieve pressure. This behavior is fundamentally viscoelastic, meaning the sheet acts as both a solid and a fluid.
When a paper web is stretched during printing, the tension drops even if the length remains the same.
Molecular Rearrangement
High humidity environments accelerate these changes because water molecules act as plasticizers that increase the mobility of the polymer chains. As moisture enters the amorphous regions of the cellulose, the stress relaxation kinetics speed up. This can lead to a loss of tension in wound rolls or the loosening of corrugated box structures under load.
The process is typically logarithmic, with the most rapid decay occurring immediately after the strain is applied. Heat also contributes to this molecular shifting. Cold storage conversely slows the decay.
Mechanical Significance
Engineers use this data to predict the long term performance of heavy duty packaging. If the stress relaxes too quickly, the package may lose its stacking strength. Standard tests involve clamping a strip of paper and measuring the force over several minutes.
This helps in selecting the right pulp blend for shipping containers.