Structural Zone
Botanical structure within the secondary wall of a wood fiber contains the highest concentration of cellulose and provides the primary mechanical strength to the plant. The s2 layer is the thickest of the three secondary wall partitions and features microfibrils oriented at a relatively steep angle to the fiber axis. Its thickness and composition determine the tensile strength and stiffness of the pulp produced from the timber.
Microfibril Orientation
Papermaking characteristics are heavily influenced by the microfibril angle found within this specific structural zone. In the s2 layer, the orientation of cellulose crystals governs how the fiber expands or contracts when it absorbs water. Fibers with a low angle in this layer are typically stiffer and produce paper with higher dimensional stability.
High angle configurations result in fibers that are more flexible but have lower tensile strength. This variation is often linked to the difference between earlywood and latewood, where the latter typically possesses a thicker and more dominant wall section.
Process Resilience
Refining and chemical treatments target the accessibility of the polymers located in the outer regions of the cell wall. While the primary wall and the s1 layer act as barriers, the bulk of the s2 layer must be reached by pulping liquors to dissolve the lignin holding the fibers together. The integrity of this layer after the pulping process dictates the final quality of the paper.